The difference between drying (curing) principle and equipment
UV Varnish is based on an initiator in varnish that absorbs UV light, generates free radicals, initiates the reaction of monomers and oligomers, and cures. A domestic laboratory curing equipment can be 20,000 RMB, domestic production equipment about 20-30 million RMB.
EB Varnish is under the intense bombardment of an electron beam, and the double bond on the monomer and oligomer is forcibly opened, generating free radicals and completing the polymerization. An imported laboratory EB curing device needs about 10-20 million dollars, while the production equipment is between 50-80 million dollars.
At present, the core technology of EB curing equipment is in the hands of a few foreign companies. Due to the small volume production of such equipment, the price is high. It is believed that if the technology is used universally, a reasonable price should be between 30-50 million US dollars. If the manufacturing technology of the device is mastered by Taiwan or domestic counterparts, it is believed that the price will be lower.
·The difference of smell
Both UV oils and EB oils do not contain solvents, so odor problems during construction do not exist. The so-called smell mainly refers to the residual odor on the printed surface. There are two sources of residual odors in UV oils: residual initiators and reactive monomers, and other small-molecule materials generated after the initiator reacts. The UV oil initiator is modified and the reaction is increased. The odor will improve, but it cannot be completely removed.
There is no initiator in the EB varnish, and the reaction degree exceeds 98%, so there will be no residual odor problem like the UV oil.
·The difference of yellowing resistance
We know that paper that has been treated with UV oil will gradually turn yellow after it has been left for a long time. The main reason is that residual initiator and initiator products absorb ultraviolet light, use expensive initiators or add UV absorbers to UV oils. It will help, but it will not be completely yellowed. EB Varnish does not use initiators, so this problem does not exist.
·Discoloration of the ink
The UV lamp generates infrared rays, and also generates infrared rays, which causes the surface temperature of the paper that has been painted to be high. Because the production efficiency must be ensured, the paper is piled together when the temperature is too low, and the paper in the inner layer will be 30- At a temperature of 60°C for a while, some inks with poor heat resistance will change color. In addition to the effect of temperature, initiators in UV oils still maintain a certain activity at relatively high temperatures and may react chemically with some of the active substances in the ink. This is also the cause of discoloration of the ink caused by UV oils. one. The improvement of UV lamps, reflectors, and cooling systems will solve the problem of ink discoloration to some extent, but it is also a solution to the problem.
In the curing process of EB varnish, the curing device does not generate infrared rays during the generation of the electron beam, and the temperature problem is well solved. Therefore, the e-beam curing is a real cold energy source and is more suitable for some heat-sensitive substrates.
·Comparison of curing degree
In order to understand the degree of solidification of UV and UV oils, the concept of gelation rate was introduced here. Its measuring method was: Varnish was made into a coating film with a thickness of 100 μm, and the cured coating film quality W0 was recorded with acetone. After extraction for 48 hours and vacuum drying at 50°C for 8 hours, the extracted mass Wg was recorded. Then calculated as follows:
Gel rate = Wg/W0 ×
The higher the gelation rate, the higher the degree of curing. The following figure shows the comparison of the degree of curing of typical EB varnish and UV varnish.
Visible, UV oil, regardless of how to increase energy, the curing degree is only about 75%, UV oil normal construction energy is 50-100mJ/cm2, which means that we currently use the UV oil, there will be 25% to 30% on the surface of the print The residue of small molecules, these small molecules, on the one hand to reduce the physical properties of the product, on the one hand, there are serious security risks, if it may lead to human skin allergies.
The curing energy of EB varnish reaches 40 kGy (expressing unit of electron beam energy), the curing degree can reach more than 98%, and the physical properties and safety are well solved.
· The difference between scratch resistance, abrasion resistance and explosion-proof wire
Anti-grinding: Because the degree of curing of EB varnish is much higher than that of UV varnish, plus the reason of oxygen inhibition during UV curing, the curing of UV varnish is lower than that of the inside, so the same coating film is used. Under the condition of hardness, the resistance of UV varnish is far less than that of EB varnish. Of course, increasing the hardness of UV varnish, adding anti-abrasive fillers and auxiliaries, etc., can improve the anti-gripping property of UV oil, but this will bring the explosion-proof and linear sacrifice of UV oil.
Abrasion resistance: We know that the abrasion resistance is related to the flexibility of the coating film. The greater the toughness, the more wearable the coating film, such as automotive tire (SBS rubber material) and sports shoe sole (PU polyurethane material), etc. Insufficient curing of varnish does not result in a coating with good flexibility. Therefore, the wear resistance of UV varnish cannot be compared with EB varnish.
Explosion-proof linearity: Once tested, the initiator in the UV oil formulation was removed and changed to EB varnish. The EB varnish was found to have a lower explosion-resistant linearity than the UV oil. If this is the case, it would be a big mistake. Because the curing degree of EB varnish is higher than that of UV oil by nearly 30%, the higher the degree of curing, the greater the hardness of the product, the easier it will be broken, and the antiknock linearity will be deteriorated.
UV Varnish is based on an initiator in varnish that absorbs UV light, generates free radicals, initiates the reaction of monomers and oligomers, and cures. A domestic laboratory curing equipment can be 20,000 RMB, domestic production equipment about 20-30 million RMB.
EB Varnish is under the intense bombardment of an electron beam, and the double bond on the monomer and oligomer is forcibly opened, generating free radicals and completing the polymerization. An imported laboratory EB curing device needs about 10-20 million dollars, while the production equipment is between 50-80 million dollars.
At present, the core technology of EB curing equipment is in the hands of a few foreign companies. Due to the small volume production of such equipment, the price is high. It is believed that if the technology is used universally, a reasonable price should be between 30-50 million US dollars. If the manufacturing technology of the device is mastered by Taiwan or domestic counterparts, it is believed that the price will be lower.
·The difference of smell
Both UV oils and EB oils do not contain solvents, so odor problems during construction do not exist. The so-called smell mainly refers to the residual odor on the printed surface. There are two sources of residual odors in UV oils: residual initiators and reactive monomers, and other small-molecule materials generated after the initiator reacts. The UV oil initiator is modified and the reaction is increased. The odor will improve, but it cannot be completely removed.
There is no initiator in the EB varnish, and the reaction degree exceeds 98%, so there will be no residual odor problem like the UV oil.
·The difference of yellowing resistance
We know that paper that has been treated with UV oil will gradually turn yellow after it has been left for a long time. The main reason is that residual initiator and initiator products absorb ultraviolet light, use expensive initiators or add UV absorbers to UV oils. It will help, but it will not be completely yellowed. EB Varnish does not use initiators, so this problem does not exist.
·Discoloration of the ink
The UV lamp generates infrared rays, and also generates infrared rays, which causes the surface temperature of the paper that has been painted to be high. Because the production efficiency must be ensured, the paper is piled together when the temperature is too low, and the paper in the inner layer will be 30- At a temperature of 60°C for a while, some inks with poor heat resistance will change color. In addition to the effect of temperature, initiators in UV oils still maintain a certain activity at relatively high temperatures and may react chemically with some of the active substances in the ink. This is also the cause of discoloration of the ink caused by UV oils. one. The improvement of UV lamps, reflectors, and cooling systems will solve the problem of ink discoloration to some extent, but it is also a solution to the problem.
In the curing process of EB varnish, the curing device does not generate infrared rays during the generation of the electron beam, and the temperature problem is well solved. Therefore, the e-beam curing is a real cold energy source and is more suitable for some heat-sensitive substrates.
·Comparison of curing degree
In order to understand the degree of solidification of UV and UV oils, the concept of gelation rate was introduced here. Its measuring method was: Varnish was made into a coating film with a thickness of 100 μm, and the cured coating film quality W0 was recorded with acetone. After extraction for 48 hours and vacuum drying at 50°C for 8 hours, the extracted mass Wg was recorded. Then calculated as follows:
Gel rate = Wg/W0 ×
The higher the gelation rate, the higher the degree of curing. The following figure shows the comparison of the degree of curing of typical EB varnish and UV varnish.
Visible, UV oil, regardless of how to increase energy, the curing degree is only about 75%, UV oil normal construction energy is 50-100mJ/cm2, which means that we currently use the UV oil, there will be 25% to 30% on the surface of the print The residue of small molecules, these small molecules, on the one hand to reduce the physical properties of the product, on the one hand, there are serious security risks, if it may lead to human skin allergies.
The curing energy of EB varnish reaches 40 kGy (expressing unit of electron beam energy), the curing degree can reach more than 98%, and the physical properties and safety are well solved.
· The difference between scratch resistance, abrasion resistance and explosion-proof wire
Anti-grinding: Because the degree of curing of EB varnish is much higher than that of UV varnish, plus the reason of oxygen inhibition during UV curing, the curing of UV varnish is lower than that of the inside, so the same coating film is used. Under the condition of hardness, the resistance of UV varnish is far less than that of EB varnish. Of course, increasing the hardness of UV varnish, adding anti-abrasive fillers and auxiliaries, etc., can improve the anti-gripping property of UV oil, but this will bring the explosion-proof and linear sacrifice of UV oil.
Abrasion resistance: We know that the abrasion resistance is related to the flexibility of the coating film. The greater the toughness, the more wearable the coating film, such as automotive tire (SBS rubber material) and sports shoe sole (PU polyurethane material), etc. Insufficient curing of varnish does not result in a coating with good flexibility. Therefore, the wear resistance of UV varnish cannot be compared with EB varnish.
Explosion-proof linearity: Once tested, the initiator in the UV oil formulation was removed and changed to EB varnish. The EB varnish was found to have a lower explosion-resistant linearity than the UV oil. If this is the case, it would be a big mistake. Because the curing degree of EB varnish is higher than that of UV oil by nearly 30%, the higher the degree of curing, the greater the hardness of the product, the easier it will be broken, and the antiknock linearity will be deteriorated.
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